How can I get point values from the services?

In case you would like to get point values at some location (e.g. reflectance, NDVI, etc.) you can use the GetFeatureInfo request (e.g. “Identify features” or “feature info” in various GIS applications), e.g:

https://services.sentinel-hub.com/ogc/wms/<INSTANCE_ID>?SERVICE=WMS&VERSION=1.3.0&REQUEST=GetFeatureInfo&I=0&J=0&QUERY_LAYERS=NDVI&INFO_FORMAT=application/json&BBOX=38.55105530425345,-7.883667078518689,38.55269383803389,-7.885252872445627&CRS=EPSG:4326&MAXCC=100&WIDTH=1&HEIGHT=1&TIME=2017-03-16

Check also Statistical API.